Ultrasound-assisted emulsification–microextraction and spectrophotometric determination of cobalt, nickel and copper after optimization based on Box-Behnken design and chemometrics methods
نویسندگان
چکیده
منابع مشابه
Preconcentration based dispersive liquid-liquid microextraction for spectrophotometric determination of zinc in natural water and human blood after multivariate optimization based on Box-Behnken design
A new simple and rapid dispersive liquid-liquid microextraction has been applied to preconcentrate tracelevels of zinc as a prior step to its determination by spectrophotometric method. In the proposed method, 4-(2-pyridylazo) resorcinol (PAR) is used as a chelating agent, and chloroform and ethanol are selected asextraction and dispersive solvent. The optimization strategy is carried out by us...
متن کاملSpectrophotometric simultaneous determination of nickel, cobalt and copper by orthogonal signal correction–partial least squares
A method for the simultaneous spectrophotometric determination of nickel, cobalt and copper based on theformation of their complexes with 2-(2-Thiazolylazo)-p-Cresol (TAC) in micellar media of Triton X-100 isproposed. The absorbance spectra were recorded in the range of 500 to 800 nm. The linear concentrationrange for nickel, cobalt and copper in solution calibration sets were 0.05–1.80, 0.10–6...
متن کاملSpectrophotometric Determination of Copper and Nickel in Marine Brown Algae after Preconcentration with Surfactant Assisted Dispersive Liquid-Liquid Microextraction
A simple, fast and effective pre-concentration method for the determination of Cu (copper) and Ni (nickel) was developed using a Surfactant Assisted Dispersive Liquid-Liquid Microextraction (SA-DLLME) coupled by UV-Vis spectrophotometry in marine brown algae. The complexing agent was 1- (2- pyridylazo) – 2 - naphthol (PAN).The effects of various experimental parameters in the extraction ste...
متن کاملpreconcentration based dispersive liquid-liquid microextraction for spectrophotometric determination of zinc in natural water and human blood after multivariate optimization based on box-behnken design
a new simple and rapid dispersive liquid-liquid microextraction has been applied to preconcentrate tracelevels of zinc as a prior step to its determination by spectrophotometric method. in the proposed method, 4-(2-pyridylazo) resorcinol (par) is used as a chelating agent, and chloroform and ethanol are selected asextraction and dispersive solvent. the optimization strategy is carried out by us...
متن کاملdetermination of olanzapine and thiourea using electrodes modified by dna and film of copper-cobalt hexacyanoferrate & investigation of electro-oxidation of some catechol derivatives in the presence of 4-phenylsemicarbazid
چکیده هدف از این کار بررسی الکترواکسیداسیون کتکول و مشتقات آن در حضور 4-فنیل سمی کاربامازید بوده است اکسیداسیون کتکولها ترکیبات نا پایدار کینونها را تولید می کنند که این ترکیبات می تواند در واکنش مایکل بعنوان پذیرنده نوکلئوفیل عمل نمایند. در ادامه اکسایش کتکولهای (a-c1) را درحضور 4-فنیل سمی کاربامازید در محلول آب/استونیتریل (90/10)بوسیله ولتامتری چرخه ای و کولن متری در پتانسیل ثابت مورد بررسی ...
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ژورنال
عنوان ژورنال: Polish Journal of Chemical Technology
سال: 2018
ISSN: 1899-4741
DOI: 10.2478/pjct-2018-0004